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Geometrical parameters, as well as bond, dipole, quadrupole and polarizability moments of the molecule Re-N, are calculated at the MP4 level of theory. From these results, the vibrational spectrum of the rhenium-nitrogen molecule is obtained. The chemical shifts in the infrared and visible spectra of the Re-N complex are calculated. We found that the complex behaves as a polarizable molecule. The total electronic polarizability is calculated for both isolated Re and N, and for Re-N, as well. These results show that the Re-N molecule is a polarizable molecule. The existence of a charge transfer between rhenium and nitrogen atoms is discussed in terms of their chemical shifts, infrared and visible spectra and total polarizability./*
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